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Chemistry 12: Gas Laws Avogadro's Law

Lorenzo Romano Amedeo Carlo Avogadro 1776-1876
Count of Quaregna and Cerreto
As a tribute to him the Avogadro Constant was named after his gas law work: 6.022 x 10^23
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The AVOGADRO CONSTANT

The Avogadro number is the number of particles (atoms, molecules or ions) in ONE MOLE of the substance

Prior Knowledge/Preview
Units of volume
1 mL = 1 cm^3
1000 mL = 1 L  =  1 dm^3
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MOLAR VOLUME at STP
volume of a gas at STP (Standard Temperature and Pressure), which is equal to 22.4 L for 1 mole of any ideal gas at a temperature equal to 273.15 K and a pressure equal to 1.00 atm
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Aerospace CONNECTIONS:
Gas Laws in aerospace
Applications and examples:
   Fuels--moles reacting
   Breathing in Space--volume/moles in a space capsule
   Temperature changes in Space
   Pressure and Altitude

The AVOGADRO LAW states that the volume of a gas varies directly with the number of moles of a gas (at the same temperature and pressure)

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EQUAL volumes of different gases

SAME number of moles

SAME number of particles

Under same conditions of temperature and pressure

If all contained 1 mole, the mass of each gas would be the MOLAR MASS in g

AVOGADRO"S LAW

Volume is directly proportional to the number of moles of a gas

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Volume = V      Number of moles = n

              V      n

              V  =  constant x n

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Avogadro's Law ACTIVITY

             

                  with five balloons containing different noble gases

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  • QUESTION: If you have 45.0 g argon, and all the balloons are the same size, under the same conditions of temperature and pressure, what masses are in each of the other balloons?

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QUESTION: If you ignore the mass of the actual latex balloon (the uninflated balloon), and just consider the mass of gas itself, which of the balloons would float in air? Reminder: take air’s composition to be 80% nitrogen and 20% oxygen with a molar mass of 28.96 g/mol.

Gas Laws

Avogadro's Law

Boyle's Law

Charles's Law

Pressure Law

Gay-Lussac's Law

Ideal Gas equation

Ideal gases

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